A NOVEL HOST GUEST SYSTEM WITH A NANOMETER LARGE CAVITY FOR ANIONS AND CATIONS - [2NH4+,2CL-SUBSET-OF-V14O22(OH)4(H2O)2-(C6H5PO3)8]6-

被引：82

作者：

MULLER, A

HOVEMEIER, K

ROHLFING, R

机构：

[1] Fakultät Für Chemie, Universität, Bielefeld, D-W-4800

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 09期

关键词：

D O I：

10.1002/anie.199211921

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A polytopic host for several cations and anions or cation/anion aggregates was previously unknown. The anion of the title (structure depicted on the right) is a host/guest system in which the "host"-the shell-consists of electrophilic and nucleophilic components. The cation/anion aggregate (NH4)2Cl2, a section of the NH4Cl ion lattice, is incorporated as "guest".

引用

页码：1192 / 1195

页数：4

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