STRUCTURE OF LA5MO32O54 CONTAINING TRANS BICAPPED MO8 OCTAHEDRAL CLUSTERS AND TRICLUSTER MO-7-MO-10-MO-7 CHAIN FRAGMENTS

被引：7

作者：

GALL, P

TOUPET, L

GOUGEON, P

机构：

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1993年 / 49卷

关键词：

D O I：

10.1107/S0108270193001532

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structure of La5Mo32O54 contains the new trans-face bicapped Mo8 cluster and a novel Mo24 tricluster chain fragment composed of one Mo10 and two Mo7 clusters. The Mo8 and Mo24 clusters are connected by bridging O atoms and are arranged in layers parallel to the ac plane. The three crystallographically distinct La3+ ions have coordination numbers of 11 or 12 with an environment in each case based on a distorted cubo-octahedron.

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页码：1580 / 1584

页数：5

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