KINETICS OF POLYMER DECOMPOSITION

被引：14

作者：

DANFORTH, JD ^{[1
]}

TAKEUCHI, T ^{[1
]}

机构：

[1] NAGOYA UNIV,CHIKUSA,NAGOYA,JAPAN

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 1973年 / 11卷 / 09期

关键词：

CHEMICAL REACTIONS - Reaction Kinetics;

D O I：

10.1002/pol.1973.170110901

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Kinetic equations have been developed for polymers that decompose by the zipper mechanism. The usual assumption of steady state kinetics has not been made. Plots of the fraction decomposed alpha , as a function of time demonstrate a variety of patterns depending upon the relative values of the fraction k//1, of chains becoming activated per second and the fraction k//2 of an activated chain that decomposes per second.

引用

页码：2083 / 2090

页数：8