THE LUMINESCENCE OF DIVALENT AND TRIVALENT RARE-EARTH IONS IN THE CRYSTALLINE AND GLASS MODIFICATIONS OF SRB4O7

被引：68

作者：

VERWEY, JWM

DIRKSEN, GJ

BLASSE, G

机构：

[1] Debye Research Institute, University of Utrecht, 3508 TA Utrecht

来源：

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS | 1992年 / 53卷 / 03期

关键词：

LUMINESCENCE; EFFICIENCY; GLASS; CRYSTAL COMPARISON;

D O I：

10.1016/0022-3697(92)90170-I

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The luminescence of several rare earth ions in the crystalline and glass modification of SrB4O7 is investigated, with a special stress on the transitions of the broad-band type. The luminescence of all the three divalent rare earth ions is reported and discussed. Yb2+ and EU2+ show mainly broad-band emissions while Sm2+ shows line emissions of the 5D0 level to the 7F(J), levels. The results lead to some conclusions about the factors which determine the luminescence efficiency in glasses.

引用

收藏

页码：367 / 375

页数：9

相关论文

共 27 条

[1] LUMINESCENCE OF INORGANIC SOLIDS - FROM ISOLATED CENTERS TO CONCENTRATED SYSTEMS [J].

BLASSE, G .

PROGRESS IN SOLID STATE CHEMISTRY, 1988, 18 (02) :79-171

[2] THE LUMINESCENCE OF YTTERBIUM(II) IN STRONTIUM TETRABORATE [J].

BLASSE, G ;

DIRKSEN, GJ ;

MEIJERINK, A .

CHEMICAL PHYSICS LETTERS, 1990, 167 (1-2) :41-44

[3] EFFECT OF R3+ IONS ON THE STRUCTURE AND PROPERTIES OF LANTHANUM BORATE GLASSES [J].

CHAKRABORTY, IN ;

DAY, DE .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1985, 68 (12) :641-645

[4]

GREIS O, 1982, HDB PHYSICS CHEM RAR, pCH45

[5]

Guzzi M., 1973, Journal of Luminescence, V6, P270, DOI 10.1016/0022-2313(73)90023-9

[6] A STUDY OF THE SENSITIZER IN THE LUMINESCENT SYSTEMS (Y,GD)2O2SO4-BI,TB AND LI6(Y,GD)(BO3)3CE3+,TB, LI6(Y,GD)(BO3)3PR3+,TB, LI6(Y,GD)(BO3)3BI3+,TB [J].

KILIAAN, HS ;

BLASSE, G .

MATERIALS CHEMISTRY AND PHYSICS, 1987, 18 (1-2) :155-170

[7] LUMINESCENCE AND ABSORPTION OF TB3+ IN MO.AL2O3.B2O3.TB2O3 GLASSES [J].

KROL, DM ;

VANSTAPELE, RP ;

HAANSTRA, JH ;

POPMA, TJA ;

THOMAS, GE ;

VINK, AT .

JOURNAL OF LUMINESCENCE, 1987, 37 (06) :293-302

[8] HIGH-PRESSURE MEASUREMENTS AT MODERATE TEMPERATURES IN A DIAMOND ANVIL CELL WITH A NEW OPTICAL SENSOR - SRB4O7-SM2+ [J].

LACAM, A ;

CHATEAU, C .

JOURNAL OF APPLIED PHYSICS, 1989, 66 (01) :366-372

[9] LUMINESCENCE AND ENERGY-TRANSFER IN LEAD-ACTIVATED STRONTIUM HALOBORATE (SR,PB)2B5O9CL, (SR,PB)2B5O9BR [J].

MEIJERINK, A ;

JETTEN, H ;

BLASSE, G .

JOURNAL OF SOLID STATE CHEMISTRY, 1988, 76 (01) :115-123

[10] LUMINESCENCE AND ENERGY MIGRATION IN (SR,EU)B4O7, A SYSTEM WITH A 4F7-4F65D CROSSOVER IN THE EXCITED-STATE [J].

MEIJERINK, A ;

NUYTEN, J ;

BLASSE, G .

JOURNAL OF LUMINESCENCE, 1989, 44 (1-2) :19-31