HETEROGENEOUS ENANTIOSELECTIVE DIHYDROXYLATION OF ALIPHATIC OLEFINS - A COMPARISON BETWEEN DIFFERENT POLYMERIC CINCHONA ALKALOID DERIVATIVES

被引：31

作者：

PETRI, A ^{[1
]}

PINI, D ^{[1
]}

SALVADORI, P ^{[1
]}

机构：

[1] UNIV PISA,DIPARTIMENTO CHIM & CHIM IND,CNR,I-56126 PISA,ITALY

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 09期

关键词：

D O I：

10.1016/0040-4039(95)00045-E

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Two new polymeric cinchona alkaloid derived ligands were synthetized and used in the asymmetric dihydroxylation of aliphatic olefins, obtaining far the first time in the reaction performed in the heterogeneous phase enantioselectivity up to 88%.

引用

页码：1549 / 1552

页数：4

共 12 条

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[12] THE OSMIUM-CATALYZED ASYMMETRIC DIHYDROXYLATION - A NEW LIGAND CLASS AND A PROCESS IMPROVEMENT [J].

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CRISPINO, GA ;

HARTUNG, J ;

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