PHOTOCHEMICAL PRODUCTION OF CARBONYL SULFIDE IN SEAWATER AND ITS EMISSION TO THE ATMOSPHERE

被引：70

作者：

Andreae, Meinrat ^{[1
]}

Feree, Ronald ^{[1
,2
]}

机构：

[1] Florida State Univ, Dept Oceanog, Tallahassee, FL 32306 USA

[2] Univ Washington, Dept Atmospher Sci, Seattle, WA 98195 USA

来源：

GLOBAL BIOGEOCHEMICAL CYCLES | 1992年 / 6卷 / 02期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1029/91GB02809

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Carbonyl sulfide (COS) measurements in the surface waters of the temperate and subtropical North Atlantic and the Gulf of Mexico showed COS to be supersaturated with respect to atmospheric equilibrium at almost all locations and times investigated. Its concentration follows a pronounced diel cycle which can be modeled using a simple equation which includes hydrolysis removal and photochemical production. The concentration and ocean/atmosphere flux of COS depends strongly on marine productivity, the highest levels being found in coastal and shelf waters. Analysis of presently available data yields an estimate of 13 Gmol yr(-1) (0.41 Tg S(COS) yr(-1)) for the total flux of COS from the oceans to the atmosphere.

引用

页码：175 / 183

页数：9

共 32 条

[21] Liss P. S., 1986, ROLE AIR SEA EXCHANG, V185, P113, DOI [DOI 10.1007/978-94-009-4738-2_5, 10.1007/978-94-009-4738-2_5]
[22] STRATOSPHERIC SULFATE PRODUCTION AND THE PHOTOCHEMISTRY OF THE ANTARCTIC CIRCUMPOLAR VORTEX
OPPENHEIMER, M
[J]. NATURE, 1987, 328 (6132) : 702 - 704
[23] RADON EVASION RATES IN THE ATLANTIC AND PACIFIC OCEANS AS DETERMINED DURING THE GEOSECS PROGRAM
PENG, TH
BROECKER, WS
MATHIEU, GG
LI, YH
[J]. JOURNAL OF GEOPHYSICAL RESEARCH-OCEANS, 1979, 84 (NC5) : 2471 - 2486
[24] THE OCEANIC SOURCE OF CARBONYL SULFIDE (OCS)
RASMUSSEN, RA
KHALIL, MAK
HOYT, SD
[J]. ATMOSPHERIC ENVIRONMENT, 1982, 16 (06) : 1591 - 1594
[25] ROLE OF HETEROGENEOUS CONVERSION OF N2O5 ON SULFATE AEROSOLS IN GLOBAL OZONE LOSSES
RODRIGUEZ, JM
KO, MKW
SZE, ND
[J]. NATURE, 1991, 352 (6331) : 134 - 137
[26] GAS-EXCHANGE AND CO2 FLUX IN THE TROPICAL ATLANTIC-OCEAN DETERMINED FROM RN-222 AND PCO2 MEASUREMENTS
SMETHIE, WM
TAKAHASHI, T
CHIPMAN, DW
[J]. JOURNAL OF GEOPHYSICAL RESEARCH-OCEANS, 1985, 90 (NC4): : 7005 - 7022
[27] THE SULFUR CYCLE IN THE MARINE ATMOSPHERE
TOON, OB
KASTING, JF
TURCO, RP
LIU, MS
[J]. JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1987, 92 (D1) : 943 - 963
[28] ATMOSPHERIC OCS MEASUREMENTS ON PROJECT GAMETAG
TORRES, AL
MAROULIS, PJ
GOLDBERG, AB
BANDY, AR
[J]. JOURNAL OF GEOPHYSICAL RESEARCH-OCEANS, 1980, 85 (NC12) : 7357 - 7360
[29] OCS, STRATOSPHERIC AEROSOLS AND CLIMATE
TURCO, RP
WHITTEN, RC
TOON, OB
POLLACK, JB
HAMILL, P
[J]. NATURE, 1980, 283 (5744) : 283 - 286
[30] TURNER SM, 1985, J ATMOS CHEM, V2, P223, DOI 10.1007/BF00051074

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