NONPLANARITY AND BARRIER TO RING PUCKERING IN PHTHALAN

被引：17

作者：

CAMINATI, W ^{[1
]}

DAMIANI, D ^{[1
]}

FAVERO, LB ^{[1
]}

机构：

[1] CNR,IST SPETTROSCOPIA MOLEC,I-40126 BOLOGNA,ITALY

来源：

MOLECULAR PHYSICS | 1993年 / 79卷 / 04期

关键词：

D O I：

10.1080/00268979300101551

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

From the analysis of its rotational spectrum, phthalan appears to be non-planar with a barrier of about 40 cm-1 hindering the ring puckering of the five membered component. This result is in contrast to both a far infrared investigation (Smithson, T. L., Duckett, J. A., and Wieser, H., 1984, J. phys. Chem., 88, 1102) that suggested the molecule to be planar, and a single vibronic level fluorescence spectrum (Hassan, K. H., and Hollas, J. M., 1991, J. molec. Spectrosc. 147, 100) that suggested a barrier hindering a twisting motion.

引用

页码：699 / 708

页数：10

共 18 条

[1]

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