DIYNE COORDINATION CHEMISTRY .3. ON THE REACTIONS OF [RUCLH(CO)(PPH3)3] WITH BIS(ALKYNYL)MERCURIALS

被引：41

作者：

HILL, AF ^{[1
]}

HARRIS, MCJ ^{[1
]}

MELLING, RP ^{[1
]}

机构：

[1] UNIV WARWICK,DEPT CHEM,COVENTRY CV4 7AL,W MIDLANDS,ENGLAND

来源：

POLYHEDRON | 1992年 / 11卷 / 07期

关键词：

D O I：

10.1016/S0277-5387(00)86010-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of [RuClH(CO)(PPh3)3] with bis(alkynyl)mercurials [Hg(C = CR)2] (R = Ph, C6H4Me-4, nC4H9, CMe2OH) leads to the formation of the coordinatively unsaturated but-3-en-l-yn-3-yl complexes [Ru{C(C = CR) = CHR}Cl(CO)(PPh3)2].

引用

页码：781 / 787

页数：7

共 22 条

[1]

ALCOCK NW, UNPUB ORGANOMETALLIC

[2] CYCLOPENTADIENYLRUTHENIUM PHOSPHINE COMPLEXES .2. REACTIONS BETWEEN HYDRIDOBIS(TRIPHENYLPHOSPHINE) (PI-CYCLOPENTADIENYL)RUTHENIUM AND ACETYLENES [J].

BLACKMORE, T ;

BRUCE, MI ;

STONE, FGA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1974, (01) :106-112

[3]

BOHLE DS, 1988, J ORGANOMET CHEM, V358, P411

[4]

CARTWRIGHT J, UNPUB

[5]

DAUTER Z, 1986, J CHEM SOC DA, V4, P433

[6] COORDINATION, OLIGOMERIZATION AND TRANSFER HYDROGENATION OF ACETYLENES BY SOME RUTHENIUM AND OSMIUM CARBOXYLATES - CRYSTAL AND MOLECULAR-STRUCTURES OF BIS(TRIFLUOROACETATO)CARBONYL-(METHANOL)BIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) AND (1,4-DIPHENYLBUT-1-EN-3-YN-2-YL)TRIFLUOROACETATO-(CARBONYL)BIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II)R [J].

DOBSON, A ;

MOORE, DS ;

ROBINSON, SD ;

HURSTHOUSE, MB ;

NEW, L .

POLYHEDRON, 1985, 4 (06) :1119-1130

[7] COORDINATION, OLIGOMERIZATION AND TRANSFER HYDROGENATION OF ACETYLENES BY SOME RUTHENIUM AND OSMIUM CARBOXYLATO COMPLEXES - CRYSTAL AND MOLECULAR-STRUCTURE OF (1,4-DIPHENYLBUT-1-EN-3-YN-2-YL)TRIFLUOROACETATO(CARBONYL)BIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) [J].

DOBSON, A ;

MOORE, DS ;

ROBINSON, SD ;

HURSTHOUSE, MB ;

NEW, L .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1979, 177 (02) :C8-C12

[8] SYNTHESIS AND STRUCTURE OF FECL(C=CPH)(DMPE)2 [J].

FIELD, LD ;

GEORGE, AV ;

HAMBLEY, TW .

INORGANIC CHEMISTRY, 1990, 29 (22) :4565-4569

[9] FORMATION OF NEW TYPES OF C4-LIGANDS THROUGH OXIDATIVE COUPLING OF 2 METAL-BOUND ALKINYL GROUPS [J].

GOTZIG, J ;

OTTO, H ;

WERNER, H .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 287 (02) :247-254

[10]

HARIS MCJ, 1991, ORGANOMETALLICS, V10, P3903

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