It has been shown that the carbonation of Ca(OH)2 takes place with a yield close to 100% at CO2 pressures ranging from 20 Torr to 1 atmosphere, while the conversions obtained from anhydrous CaO range from 22% at 20 Torr of CO2 up to 79% at 1 atmosphere. Moreover. the carbonation of CaO occurs at temperatures higher than those at which the carbonation of corresponding hydroxide occurs. Thus, at a CO2 pressure of 1 atmosphere the hydroxide is quite carbonated at 700-degrees-C, while only 60% of CaO is converted into CaCO3 under similar conditions. It has been concluded that the effect of aging is minimized if the carbonation of CaO is conducted in such a way that it takes place through Ca(OH)2 as a by-product.
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WENTWORTH WE, 1976, SOL ENERGY, V18, P205, DOI 10.1016/0038-092X(76)90019-0