STRUCTURE OF AN IRIDIUM(I) COMPLEX OF TRIS-(2,6-DIMETHOXYPHENYL)PHOSPHINE, [IR(C8H12)-(C5H5N)(P(2,6-(CH3O)2C6H3)3)][PF6]

被引:5
作者
BEDFORD, RB
CHALONER, PA
HITCHCOCK, PB
机构
关键词
D O I
10.1107/S0108270193000253
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The structure of (eta4-1,5-cyclooctadiene)(pyridine)-[tris(2,6-dimethoxyphenyl)phosphine]iridium(1) hexafluorophosphate shows approximately square-pyrimidal geometry at the Ir atom with one of the methoxy groups of the phosphine ligand being weakly bound in the apical position [Ir...O = 2.724 (6) angstrom].
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页码:1461 / 1463
页数:3
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