TAILORED SYNTHESIS OF HYDROCARBON CHAINS VIA C-C COUPLING REACTIONS OF DIYNES AND ALKYNES ON THE SQUARE FACE OF AN RU4P CLUSTER

被引：49

作者：

CORRIGAN, JF ^{[1
]}

DOHERTY, S ^{[1
]}

TAYLOR, NJ ^{[1
]}

CARTY, AJ ^{[1
]}

机构：

[1] UNIV WATERLOO,GUELPH WATERLOO CTR GRAD WORK CHEM,DEPT CHEM,WATERLOO CAMPUS,WATERLOO N2L 3G1,ONTARIO,CANADA

来源：

ORGANOMETALLICS | 1992年 / 11卷 / 10期

关键词：

D O I：

10.1021/om00046a002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The mixed transition-metal-main-group cluster Ru4(mu3-PPh)(CO)13 (1) trimerizes diynes and codimerizes alkynes and diynes to form novel 12- and 8-carbon-atom hydrocarbyls. The X-ray structures of Ru4(CO)8(mu4-PPh)[eta1:eta1:eta2:eta2-(Ph)CC(C=CPh)C(Ph)C-eta4-CC(Ph)C(Ph)C-(C=CPh)] (2) and Ru4(CO)10(mu-CO)2[mu4-eta1(P):eta1(P):eta1-(P):eta1(C):eta2(C)-P(Ph)C(C=CPh)C(Ph)] (3) are reported.

引用

页码：3160 / 3163

页数：4

共 33 条

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