TI-OET BOND-CLEAVAGE IN THE REACTION OF TI(OET)4 WITH MANGANESE CARBONYL HYDRIDE - THE NEW HETEROBIMETALLIC COMPLEX [TI3(OET)6(MU-2-OET)3(MU-3-OET)2]+[MN(CO)5]-

被引：1

作者：

BELYI, AA

KUZNETSOV, VF

BLUMENFELD, AL

机构：

[1] A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, 117813

来源：

RUSSIAN CHEMICAL BULLETIN | 1993年 / 42卷 / 08期

关键词：

TITANIUM ETHOXIDE; MANGANESE CARBONYL HYDRIDE; HETEROBIMETALLIC COMPLEX;

D O I：

10.1007/BF00699918

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Titanium ethoxide, which is trimeric in organic solvents, reacts with HMn(CO)5 to eliminate ethanol and to form a heterobimetallic complex. The cationic part of the latter contains three titanium atoms bound by mu2- and mu3-OEt bridging groups.

引用

页码：1300 / 1303

页数：4