Layered and pillared zirconium phosphate-phosphonates and their inclusion chemistry

被引：41

作者：

Alberti, G

Costantino, U

Dionigi, C

MurciaMascaros, S

Vivani, R

机构：

[1] Dept. of Chemistr, University of Perugia via Elce di Sotto 8

来源：

SUPRAMOLECULAR CHEMISTRY | 1995年 / 6卷 / 1-2期

关键词：

D O I：

10.1080/10610279508032517

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

After a brief account on previous results obtained in this Laboratory in the field of layered and pillared alpha- and gamma-zirconium phosphonates, the perspectives for a development of a ''molecular recognition'' in porous and in layered solids are examined. In particular, the preparation and the preliminary characterisation of some new zirconium phosphonates more specifically designed for a ''molecular recognition'', such as: a) layered and pillared derivatives of gamma-zirconium phosphate containing crown ethers in the interlayer region, b) alpha-layered zirconium phosphate containing chiral centres anchored to its surface and c) pillared derivatives of gamma-zirconium phosphate containing non rigid pillars, are reported and discussed.

引用

页码：29 / 40

页数：12

共 53 条

[11] CRYSTALLINE ZR(R-PO3)2 AND ZR(R-OPO3)2 COMPOUNDS (R=ORGANIC RADICAL) - NEW CLASS OF MATERIALS HAVING LAYERED STRUCTURE OF ZIRCONIUM-PHOSPHATE TYPE [J].