THE ENANTIOSPECIFIC NICHOLAS REACTION

被引：36

作者：

MUEHLDORF, AV

GUZMANPEREZ, A

KLUGE, AF

机构：

[1] Institute of Organic Chemistry, Syntex Discovery Research Mailstop R6-201, Palo Alto, CA 94304

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 47期

关键词：

NICHOLAS REACTION; ENANTIOSPECIFIC; COBALT-STABILIZED CARBOCATIONS; 1-ETHYNYLTETRALIN;

D O I：

10.1016/S0040-4039(00)78489-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The enantiospecific Nicholas reaction, i.e. cobalt-promoted Friedel-Crafts reaction leading from chiral reactant to chiral product, was demonstrated for the first time.

引用

页码：8755 / 8758

页数：4

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