SPECTROSCOPIC STUDY OF CRYSTALLINE ND2O2S OPTICAL-ABSORPTION MEASUREMENTS, CRYSTAL-FIELD ANALYSIS AND INTENSITY CALCULATIONS

被引:11
作者
CHERTANOV, M
MOUNE, OK
PIRIOU, B
DEXPERTGHYS, J
FAUCHER, M
GUITTARD, M
机构
[1] ECOLE CENT ARTS & MFG,CHIM & PHYSICOCHIM MOLEC LAB,CNRS,ERS 70,GRANDE VOIE VIGNES,F-92295 CHATENAY MALABRY,FRANCE
[2] LAB CHIM PHYS MINERALE & BIOINORGAN,F-92296 CHATENAY MALABRY,FRANCE
关键词
D O I
10.1016/0022-2313(94)90002-7
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Room temperature and low temperature optical absorption measurements are performed on Nd2O2S in crystal and powder form. The experimental oscillator strengths are deduced and compared with calculations at 8 and 300 K including the contribution of Judd-Ofelt and Jorgensen-Judd mechanisms. The global oscillator strengths are satisfactorily reproduced by considering the sum of both contributions but the relative intensities of the strong transitions are best reproduced by the Jorgensen-Judd mechanism alone.
引用
收藏
页码:231 / 246
页数:16
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