ELECTRON-PARAMAGNETIC-RESONANCE STUDIES OF LOW-SPIN D(5) TRANSITION-METAL COMPLEXES

被引：134

作者：

RIEGER, PH

机构：

[1] Department of Chemistry, Brown University, Providence

来源：

COORDINATION CHEMISTRY REVIEWS | 1994年 / 135卷

关键词：

D O I：

10.1016/0010-8545(94)80069-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A discussion of the connection between EPR parameters and the electronic structures of mononuclear low-spin d(5) complexes, including systems with orbitally degenerate ground states which undergo Jahn-Teller distortions. EPR experimental results are critically surveyed for complexes of Ti(-I), V(0), Cr(I), Mn(II), Fe(III), Co(IV), and their heavier congeners. A review with 426 references.

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页码：203 / 286

页数：84

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