THE WALL-JET RING-DISK ELECTRODE - THE MEASUREMENT OF HOMOGENEOUS RATE CONSTANTS FROM STEADY-STATE RING CURRENTS

被引：10

作者：

BRETT, CMA

BRETT, AMCFO

COMPTON, RG

FISHER, AC

TYLEY, GP

机构：

[1] UNIV OXFORD,PHYS CHEM LAB,S PARKS RD,OXFORD OX1 3QZ,ENGLAND

[2] UNIV COIMBRA,DEPT QUIM,P-3409 COIMBRA,PORTUGAL

来源：

ELECTROANALYSIS | 1991年 / 3卷 / 07期

关键词：

D O I：

10.1002/elan.1140030707

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The wall-jet ring-disc electrode is shown to provide a convenient means determining homogeneous rate constants by means of ring current measurements as a function of disc currents and electrolyte flow rates. Theory is provided for the analysis of such "collection efficiency" experiments and applied to the specific case of the bromination of anisole, where good agreement with experiment is found. Advantages with respect to the rotating ring-disc electrode are pointed out.

引用

页码：631 / 636

页数：6

共 12 条

[1]

Albery W. J., 1971, RING DISC ELECTRODES

[2] THE WALL-JET RING-DISC ELECTRODE .1. THEORY [J].