[RH2(O2CCH3)4TCNE]X POLYMERS - ISOMERS WITH EITHER 1,1 OR TRANS-1,2-TCNE BRIDGES

被引：40

作者：

COTTON, FA

KIM, Y

LU, J

机构：

[1] Department of Chemistry, Texas A and M University, College Station

来源：

INORGANICA CHIMICA ACTA | 1994年 / 221卷 / 1-2期

关键词：

CRYSTAL STRUCTURES; RHODIUM COMPOUNDS; TETRACYANOETHYLENE COMPOUNDS; POLYMERIC COMPOUNDS;

D O I：

10.1016/0020-1693(94)03971-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two different polymeric solids have been obtained by the reaction of Rh2(O2CCH3)4 with TCNE (tetracyanoethylene). Both contain infinite chains, [Rh2(O2CCH3)4(TCNE)infinity, with solvent molecules (benzene and m-xylene) occupying interstices. In compound 1 the TCNE units serve as 1,1-bridges while in the other, 2, they serve as trans-1,2-bridges. Both compounds are black.

引用

页码：1 / 4

页数：4

共 6 条

[1] PREPARATION OF TETRAAMMONIUM OCTAKIS(ISOTHIOCYANATO)DIMOLYBDENUM(II) AND STRUCTURAL CHARACTERIZATION OF 2 CRYSTALLINE HYDRATES [J].