THE 1ST UNSOLVATED CHELATE AND CUBANE-TYPE BARIUM COMPLEXES - EFFECTIVE COMPOUNDS FOR THE SOL-GEL PROCESS

被引：25

作者：

PANDEY, SK ^{[1
]}

STEINER, A ^{[1
]}

ROESKY, HW ^{[1
]}

STALKE, D ^{[1
]}

机构：

[1] UNIV GOTTINGEN,INST ANORGAN CHEM,TAMMANNSTR 4,W-3400 GOTTINGEN,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 04期

关键词：

D O I：

10.1002/anie.199305961

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Unexpectedly good solubility was found for complexes 1 and 2 prepared from barium bis(trimethylsilyl)amide. In the BaN heterocubane 2 (shown on the right, methyl groups are omitted), four of the corners are occupied by imido N atoms of the tri‐ to pentadentate phosphazene ligands. The coordination numbers of the Ba atoms range from 5 to 7. (Formula Presented.) (Formula Presented.) (Figure Presented.) Copyright © 1993 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：596 / 598

页数：3

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