CYCLOPHOSPHAZENE METAL-OXIDES, A NEW CLASS OF COMPOUNDS, AND MODEL COMPOUNDS FOR THE POLYMERIZATION OF PHOSPHAZENES

被引：25

作者：

HASSELBRING, R ^{[1
]}

ROESKY, HW ^{[1
]}

NOLTEMEYER, M ^{[1
]}

机构：

[1] UNIV GOTTINGEN,INST ANORGAN CHEM,TAMMANNSTR 4,W-3400 GOTTINGEN,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 05期

关键词：

D O I：

10.1002/anie.199206011

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The acyclic, completely N-silylated phosphazene 1 reacts with Re2O7 to form the first cyclophosphazene metal oxide 2 on elimination of siloxane. With 2,6-diisopropylphenyl isocyanate, 2 is transformed into a mixture of novel cyclophosphazene metal imides. The formation of a twelve-membered N6P4Re2 heterocycle in the process is particularly interesting, especially with regard to mechanistic aspects of the polymerization of phosphazenes.

引用

页码：601 / 603

页数：3

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