REACTION OF FULLERENE WITH BENZOCYCLOBUTENE HOMOLOGS

被引：55

作者：

TAGO, T ^{[1
]}

MINOWA, T ^{[1
]}

OKADA, Y ^{[1
]}

NISHIMURA, J ^{[1
]}

机构：

[1] GUNMA UNIV,DEPT CHEM,KIRYU,GUNMA 376,JAPAN

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 52期

关键词：

FULLERENE; DIELS-ALDER ADDUCTS; BENZOCYCLOBUTENE HOMOLOGS; PYRENE;

D O I：

10.1016/S0040-4039(00)61359-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Fullerene was easily converted to its derivatives by the treatment with benzocyclobutene homologs for 20 h at 140 degrees C. The spectroscopic analyses clearly indicate mono-[4 + 2]-cycloadduct structures of its derivatives. Isolated yields of mono- and diadducts were from 4.4 to 15.6% and from 8.1 to 5.3%, respectively.

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收藏

页码：8461 / 8464

页数：4

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