Perhaloarylmetal Chemistry. V. The Formation and Properties of Some sigma-Perhaloaryl and Methyl Derivatives of Nickel(1,2)

被引：48

作者：

Rausch, M. D. ^{[1
]}

Tibbetts, F. E. ^{[1
]}

机构：

[1] Univ Massachusetts, Dept Chem, Amherst, MA 01002 USA

来源：

INORGANIC CHEMISTRY | 1970年 / 9卷 / 03期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1021/ic50085a016

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new series of air-stable, a-bonded organic derivatives of nickel of the types [CH3(Col-le)2P](2)Ni(aryl)C1, (CH2(CeHe)(2)P2-Ni(ary1)2, and [CH3(CH3)(2)P](2)Ni(aryl)CH3 is described. Their proton nmr spectra are consistent with a trans-planar configuration in each case. Factors affecting the relative stabilites of these products are discussed.

引用

页码：512 / 516

页数：5

共 36 条

[21] CRYSTAL STRUCTURE OF TRANS-DIMESITYLBIS(DIETHYLPHENYLPHOSPHINE)COBALT(II)
OWSTON, PG
ROWE, JM
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1963, : 3411 - &
[22] PHILLIPS JR, 1964, J ORGANOMET CHEM, V2, P455
[23] Pummer W. J., 1959, J RES NAT BUR STAN A, V68A, P167
[24] FORMATION AND STRUCTURE OF A SIGMA-ARYL DERIVATIVE OF MOLYBDENUM PI-C7H7MO(CO)2C6F5
RAUSCH, MD
IGNATOWI.AK
CHURCHIL.MR
OBRIEN, TA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (12) : 3242 - &
[25] PERHALOARYL-METAL CHEMISTRY .2. PENTACHLOROPHENYLLITHIUM
RAUSCH, MD
TIBBETTS, FE
GORDON, HB
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1966, 5 (06) : 493 - &
[26] PERHALOARYLMETAL CHEMISTRY .4. FORMATION AND PROPERTIES OF SOME ORGANONICKEL DERIVATIVES OF TYPE (PI-C5H5)(R2R'P)(R'')NI
RAUSCH, MD
CHANG, YF
GORDON, HB
[J]. INORGANIC CHEMISTRY, 1969, 8 (06) : 1355 - &
[27] SHAW BR, COMMUNICATION
[28] CRYSTAL STRUCTURE OF TRANS-BIS(PHENYLETHYNYL)BIS(TRIETHYLPHOSPHINE)NICKEL(3) [P(C2H5)3]NI(C=CC6H5)2
SPOFFORD, WA
CARFAGNA, PD
AMMA, EL
[J]. INORGANIC CHEMISTRY, 1967, 6 (08) : 1553 - &
[29] Tibbetts F. E., UNPUB
[30] FLUOROCARBON DERIVATIVES OF METALS
TREICHEL, PM
STONE, FGA
[J]. ADVANCES IN ORGANOMETALLIC CHEMISTRY, 1964, 1 : 143 - 220

← 1 2 3 4 →