DIASTEREOSELECTIVITY IN NUCLEOPHILIC-ADDITION REACTIONS TO (ALPHA-BETA-DIALKOXYACYL)SILANES - AN OPERATIONALLY USEFUL ROUTE TO OPTICALLY-ACTIVE 1,2,3-SYN-TRIOLS

被引：37

作者：

CIRILLO, PF ^{[1
]}

PANEK, JS ^{[1
]}

机构：

[1] BOSTON UNIV,METCALF CTR SCI & ENGN,DEPT CHEM,BOSTON,MA 02215

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 25期

关键词：

D O I：

10.1021/jo00312a005

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

: [syn-α-Alkoxy-β-(silyloxy)acyl]silanes 3 undergo chelation-controlled nucleophilic addition reactions to produce Cram-type addition products (1,2,3-syn-triol derivatives) 4 with useful levels of diastereoselectivity. © 1990, American Chemical Society. All rights reserved.

引用

页码：6071 / 6073

页数：3

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