CATALYTIC TANDEM OXY-PALLADATION AND VINYLATION

被引：49

作者：

SEMMELHACK, MF

EPA, WR

机构：

[1] Department of Chemistry, Princeton University, Princeton

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 45期

关键词：

D O I：

10.1016/S0040-4039(00)79288-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Intramolecular oxy-palladation of hydroxy-alkenes leads to organo-Pd(II) intermediates which can be trapped by alkenes in chain extension by vinyl substitution; catalysis is efficient using a reoxidation system but the process is limited to substrates which cannot undergo beta-hydride elimination from the organo-Pd(II) intermediate.

引用

页码：7205 / 7208

页数：4

共 17 条

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