SYNTHESIS AND CHARACTERIZATION OF THE DIPHENYLFULVENE DERIVATIVE [RU6C(CO)(14)(MU(3)-SIGMA-ETA(2)ETA(3)-C(5)H(4)CPH(2))], SHOWING AN UNUSUAL FACIAL BONDING MODE AND FLUXIONALITY ON THE NMR TIMESCALE

被引：12

作者：

BLAKE, AJ ^{[1
]}

DYSON, PJ ^{[1
]}

JOHNSON, BFG ^{[1
]}

REED, D ^{[1
]}

SHEPHARD, DS ^{[1
]}

机构：

[1] UNIV EDINBURGH, DEPT CHEM, EDINBURGH EH9 3JJ, MIDLOTHIAN, SCOTLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 11期

关键词：

D O I：

10.1039/c39940001347

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The molecular structure of the octahedral cluster, [Ru6C(CO)(14)(mu(3)-sigma:eta(2):eta(3)-C(5)H(4)CPh(2))], prepared from the reaction of [Ru6C(CO)(17)] with diphenylfulvene in the presence of trimethylamine-N oxide, has been established by low-temperature single-crystal X-ray diffraction analysis; the coordination mode is unique and the compound displays highly unusual fluxional behaviour on the NMR timescale.

引用

页码：1347 / 1348

页数：2

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