VIBRATIONAL LIFETIME OF SURFACE SPECIES OF ZEOLITES BY PICOSECOND IR PULSES

被引：17

作者：

FURUKI, M ^{[1
]}

KUBOTA, J ^{[1
]}

GOTO, Y ^{[1
]}

WAKABAYASHI, F ^{[1
]}

KONDO, J ^{[1
]}

WADA, A ^{[1
]}

DOMEN, K ^{[1
]}

HIROSE, C ^{[1
]}

机构：

[1] NATL SCI MUSEUM,DEPT SCI & ENGN,TAITO KU,TOKYO,TOKYO 110,JAPAN

来源：

JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA | 1993年 / 64-5卷

关键词：

D O I：

10.1016/0368-2048(93)80087-3

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The dynamic behaviors of hydroxyl groups in zeolites, mordenite and Y-type, are studied by FT-IR and picosecond IR pulses. N-2 adsorption to form hydrogen bonding at low temperature reveales the existence of several different types of hydroxyl groups in both zeolites. The vibrational relaxation times of the OH(v=1) groups in these zeolites are compared.

引用

页码：259 / 267

页数：9

共 19 条

[1] ALUMINUM SITING IN MORDENITE AND DEALUMINATION MECHANISM [J].

BODART, P ;

NAGY, JB ;

DEBRAS, G ;

GABELICA, Z ;

JACOBS, PA .

JOURNAL OF PHYSICAL CHEMISTRY, 1986, 90 (21) :5183-5190

[2] TIME-RESOLVED MEASUREMENTS OF OH(V = 1) VIBRATIONAL-RELAXATION ON SIO2 SURFACES - ISOTOPE AND TEMPERATURE-DEPENDENCE [J].

CASASSA, MP ;

HEILWEIL, EJ ;

STEPHENSON, JC ;

CAVANAGH, RR .

JOURNAL OF CHEMICAL PHYSICS, 1986, 84 (04) :2361-2364

[3] VIBRATIONAL-RELAXATION OF ADSORBED MOLECULES - COMPARISON WITH RELAXATION RATES OF MODEL COMPOUNDS [J].

CAVANAGH, RR ;

CASASSA, MP ;

HEILWEIL, EJ ;

STEPHENSON, JC .

JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS, 1987, 5 (04) :469-472

[4] COHERENT PROCESSES AT SURFACES - FREE-INDUCTION DECAY AND PHOTON-ECHO OF THE SI-H STRETCHING VIBRATION FOR H/SI(111) [J].

GUYOTSIONNEST, P .

PHYSICAL REVIEW LETTERS, 1991, 66 (11) :1489-1492

[5] LIFETIME OF AN ADSORBATE-SUBSTRATE VIBRATION - H ON SI(111) [J].

GUYOTSIONNEST, P ;

DUMAS, P ;

CHABAL, YJ ;

HIGASHI, GS .

PHYSICAL REVIEW LETTERS, 1990, 64 (18) :2156-2159

[6] MOLECULAR VIBRATIONAL-ENERGY RELAXATION AT A METAL-SURFACE - METHYL THIOLATE ON AG(111) [J].

HARRIS, AL ;

ROTHBERG, L ;

DUBOIS, LH ;

LEVINOS, NJ ;

DHAR, L .

PHYSICAL REVIEW LETTERS, 1990, 64 (17) :2086-2089

[7] VIBRATIONAL-ENERGY RELAXATION IN A MOLECULAR MONOLAYER AT A METAL-SURFACE [J].

HARRIS, AL ;

LEVINOS, NJ .

JOURNAL OF CHEMICAL PHYSICS, 1989, 90 (07) :3878-3879

[8]

HARRIS AL, 1991, J CHEM PHYS, V94, P2483

[9] VIBRATIONAL DEACTIVATION OF SURFACE OH CHEMISORBED ON SIO2 - SOLVENT EFFECTS [J].

HEILWEIL, EJ ;

CASASSA, MP ;

CAVANAGH, RR ;

STEPHENSON, JC .

JOURNAL OF CHEMICAL PHYSICS, 1985, 82 (11) :5216-5231

[10] TEMPERATURE-DEPENDENCE OF THE VIBRATIONAL POPULATION LIFETIME OF OH(UPSILON = 1) IN FUSED-SILICA [J].

HEILWEIL, EJ ;

CASASSA, MP ;

CAVANAGH, RR ;

STEPHENSON, JC .

CHEMICAL PHYSICS LETTERS, 1985, 117 (02) :185-190

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