OXIDATION OF ALCOHOLS BY PERFLUORO-CIS-2,3-DIALKYL OXAZIRIDINES

被引：24

作者：

DESMARTEAU, DD

PETROV, VA

MONTANARI, V

PREGNOLATO, M

RESNATI, G

机构：

[1] POLITECN MILAN,DIPARTIMENTO CHIM,CNR,CTR STUDIO SOSTANZE ORG NAT,PL DA VINCI 32,I-20133 MILAN,ITALY

[2] CLEMSON UNIV,HL HUNTER CHEM LAB,CLEMSON,SC 29634

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 47期

关键词：

D O I：

10.1016/S0040-4039(00)60884-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Perfluoro-cis-2,3-dialkyloxaziridines oxidize secondary alcohols 2 to the corresponding ketones 4 at room temperature. The reaction has been carried out with uniformly high yields on simple acyclic alcohols as well as more complex substrates such as alpha-hydroxy esters, borneols, and sterols.

引用

页码：7245 / 7248

页数：4

共 10 条

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