NMR SPECTRAL STUDIES OF [ME2SN(XYP(OBU(N))2)2] (X, Y = O OR S)

被引：8

作者：

JAIN, VK ^{[1
]}

KESAVADAS, T ^{[1
]}

VATSA, C ^{[1
]}

SMITH, ME ^{[1
]}

机构：

[1] BRUKER ANALYT MESSTECHN,MSL APPLICAT LAB,W-7512 RHEINSTETTEN,GERMANY

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 1992年 / 48卷 / 11-12期

关键词：

D O I：

10.1016/0584-8539(92)80232-L

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The diorganotin compounds, [Me2Sn{OOP(OBun)2}2] (II), [Me2Sn{OSP(OBun)2}2] (III) and [Me2Sn{SSP(OBun)2}2] (IV), have been investigated by C-13, P-31 and Sn-119 solution state NMR as well as solid state NMR. On the basis of these studies it is suggested that the phosphate ligand acts in a symmetrical chelating fashion in II, while the ligands behave in an anisobidentate manner in III and IV.

引用

页码：1583 / 1587

页数：5