CRITERIA FOR THERMAL EXPLOSIONS WITH AND WITHOUT REACTANT CONSUMPTION

被引：112

作者：

BODDINGTON, T ^{[1
]}

GRAY, P ^{[1
]}

WAKE, GC ^{[1
]}

机构：

[1] UNIV LEEDS,SCH CHEM,LEEDS LS2 9JT,W YORKSHIRE,ENGLAND

来源：

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES | 1977年 / 357卷 / 1691期

关键词：

EXPLOSIONS; -; Thermodynamics;

D O I：

10.1098/rspa.1977.0176

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

Thermal explosions occur when reactions evolve heat too rapidly for a stable balance between heat production and heat loss to be preserved. Even when reactions are kinetically simple, and obey the Arrhenius equation, the differential equations for heat balance and reactant consumption cannot be solved explicitly to express temperatures and concentrations as functions of time unless strong simplifications are made. The present paper is concerned especially with the relation between the spatially uniform and distributed temperature cases, with the effect of approximations to the Arrhenius term, and with Frank-Kamenetskii's treatment of ignition.

引用

页码：403 / 422

页数：20