PREPARATION AND STRUCTURE OF (4-PICOLINIUM)2[LNCL4(H2O3]CL (LN = EU, HO)

被引：10

作者：

MACKENSTEDT, D ^{[1
]}

URLAND, W ^{[1
]}

机构：

[1] UNIV HANNOVER,INST ANORGAN CHEM,CALLINSTR 9,D-30167 HANNOVER,GERMANY

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1993年 / 619卷 / 08期

关键词：

PREPARATION; CRYSTAL STRUCTURE; COMPLEX CHLORIDES OF LANTHANIDES; PENTAGONAL BIPYRAMID;

D O I：

10.1002/zaac.19936190813

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complex water containing chlorides (4-Picolinium)2[LnCl4(H2O)3]Cl (Ln = Eu, Ho) were prepared for the first time. The crystal structures were determined on single crystals by X-ray methods. The isotypic compounds crystallize with triclinic symmetry, space group P1BAR, Z = 2. Surprisingly the structures contain the complex anions [LnCl4(H2O)3]- (Ln = Eu, Ho) where the ligands form a distorted pentagonal bipyramid, which to our knowledge has not been observed in lanthanide compounds till now.

引用

页码：1393 / 1396

页数：4

共 11 条

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ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1993, 619 (05) :893-896

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