C2H2SI ISOMERS - GENERATION BY PULSED FLASH PYROLYSIS AND MATRIX-SPECTROSCOPIC IDENTIFICATION

被引:41
作者
MAIER, G
REISENAUER, HP
PACL, H
机构
[1] Institut Für Organische Chemie, Universität Giessen, D-35392
来源
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 12期
关键词
D O I
10.1002/anie.199412481
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
To what extent can ab initio calculations be trusted? Is silacyclopropyne (1) a transition state or an energy minimum? The experimental work described here demonstrates that all four C2H2Si isomers 1–4 can exist. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany
引用
收藏
页码:1248 / 1250
页数:3
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