In a study of the level scheme of 131Cs, we have measured the γ-γ and the ce-γ directional correlations of the 496-123.7 keV and 486-133.5 keV cascades. The linear polarization at φ=90° was measured for the 496-123.7 keV and 486-133.5 keV cascades. The L-subshell ratios for the 123.7 keV transition were determined. The g-factor of the 133.5 keV level and the half-lives of the 78.7, 123.7, 133.5 and 216 keV levels were re-investigated. The spin and parity assignments derived for the 620, 133.5 and 123.7 keV levels are 1 2+, 5 2+ and 1 2+, respectively. The 620, 496, 486, 133.5 and 123.7 keV transitions are found to be of pure E2, pure M1, pure E2, (M1+(22±2)%E2) and pure E2 multipolarity, respectively. An upper limit of 192 ps for the half-life of the 216 keV level is obtained. The results are compared with theoretical estimates from the calculations of Kisslinger and Sorensen, of Freed and of Freed and Miles. © 1969.