CRESYL VIOLET CHEMISTRY AND PHOTOPHYSICS IN VARIOUS SOLVENTS AND MICELLES

被引:24
作者
ISAK, SJ
EYRING, EM
机构
[1] Department of Chemistry, University of Utah, Salt Lake City
关键词
D O I
10.1016/1010-6030(92)85008-I
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The chemical and photophysical behavior of cresyl violet perchlorate was studied in aqueous, aqueous micellar and organic solutions. In aqueous micellar solutions the fluorescence quantum yield of cresyl violet increases in sodium dodecylsulfate (SDS), whereas a dramatic decrease is observed in Triton X-100 (TX). The chemical and photophysical behavior of cresyl violet is strongly dependent on hydrogen-bond, electrostatic and acid-base interactions in solution, as well as on its hydrophobicity.
引用
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页码:343 / 358
页数:16
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