SYNTHESIS AND PROPERTIES OF PYRIDINOCALIXARENES

被引：19

作者：

BOTTINO, F ^{[1
]}

PAPPALARDO, S ^{[1
]}

机构：

[1] UNIV CATANIA,DIPARTIMENTO SCI CHIM,I-95125 CATANIA,ITALY

来源：

JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY | 1994年 / 19卷 / 1-4期

关键词：

REGIO- AND STEREOSELECTIVE O-ALKYLATIONS; CONFORMATION AND CONFORMATIONAL MOBILITY; INHERENTLY CHIRAL CALIX[4]ARENES AND ENANTIOMERIC HPLC RESOLUTION; N-OXIDE LIGANDS AND COMPLEXES;

D O I：

10.1007/BF00708976

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Several facets of pyridinocalixarene chemistry have been investigated including reaction pathways for their formation from the base-catalyzed alkylation of the parent calixarenes with PicCl.HCl, effect of the nature and identity of the base on regio- and stereoselective O-alkylations, creation of molecular asymmetry in calix[4]arenes and enantiomeric resolution, conformation and conformational mobility, and complexation.

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页码：85 / 100

页数：16

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