SYNTHESIS AND PROPERTIES OF PYRIDINOCALIXARENES

被引：19

作者：

BOTTINO, F ^{[1
]}

PAPPALARDO, S ^{[1
]}

机构：

[1] UNIV CATANIA,DIPARTIMENTO SCI CHIM,I-95125 CATANIA,ITALY

来源：

JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY | 1994年 / 19卷 / 1-4期

关键词：

REGIO- AND STEREOSELECTIVE O-ALKYLATIONS; CONFORMATION AND CONFORMATIONAL MOBILITY; INHERENTLY CHIRAL CALIX[4]ARENES AND ENANTIOMERIC HPLC RESOLUTION; N-OXIDE LIGANDS AND COMPLEXES;

D O I：

10.1007/BF00708976

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Several facets of pyridinocalixarene chemistry have been investigated including reaction pathways for their formation from the base-catalyzed alkylation of the parent calixarenes with PicCl.HCl, effect of the nature and identity of the base on regio- and stereoselective O-alkylations, creation of molecular asymmetry in calix[4]arenes and enantiomeric resolution, conformation and conformational mobility, and complexation.

引用

收藏

页码：85 / 100

页数：16

相关论文

共 59 条

[21] CALIXARENES-9 - CONFORMATIONAL ISOMERS OF THE ETHERS AND ESTERS OF CALIX[4]ARENES [J].

GUTSCHE, CD ;

DHAWAN, B ;

LEVINE, JA ;

NO, KH ;

BAUER, LJ .

TETRAHEDRON, 1983, 39 (03) :409-426

[22] CALIXARENES .22. SYNTHESIS, PROPERTIES, AND METAL COMPLEXATION OF AMINOCALIXARENES [J].

GUTSCHE, CD ;

NAM, KC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (18) :6153-6162

[23] CALIXARENES .21. THE CONFORMATIONS AND STRUCTURES OF THE PRODUCTS OF AROYLATION OF THE CALIX[4]ARENES [J].

IQBAL, M ;

MANGIAFICO, T ;

GUTSCHE, CD .

TETRAHEDRON, 1987, 43 (21) :4917-4930

[24] SYNTHESES AND ION SELECTIVITY OF ALL CONFORMATIONAL ISOMERS OF TETRAKIS((ETHOXYCARBONYL)METHOXY)CALIX[4]ARENE [J].

IWAMOTO, K ;

SHINKAI, S .

JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (26) :7066-7073

[25] HOW IS THE 1,2-ALTERNATE CONFORMER FORMED IN TETRA-O-ALKYLATION OF PARA-TERT-BUTYLCALIX[4]ARENE [J].

IWAMOTO, K ;

ARAKI, K ;

SHINKAI, S .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1991, (06) :1611-1613

[26] CONFORMATIONS AND STRUCTURES OF TETRA-O-ALKYL-PARA-TERT-BUTYLCALIX[4]ARENES - HOW IS THE CONFORMATION OF CALIX[4]ARENES IMMOBILIZED [J].

IWAMOTO, K ;

ARAKI, K ;

SHINKAI, S .

JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (16) :4955-4962

[27] SYNTHESES AND OPTICAL RESOLUTION OF CALIX[4]ARENES WITH MOLECULAR ASYMMETRY - SYSTEMATIC CLASSIFICATION OF ALL POSSIBLE CHIRAL ISOMERS DERIVABLE FROM CALIX[4]ARENE [J].

IWAMOTO, K ;

SHIMIZU, H ;

ARAKI, K ;

SHINKAI, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (10) :3997-4006

[28] SYNTHESES OF ALL POSSIBLE CONFORMATIONAL ISOMERS OF O-ALKYL-PARA-TERT-BUTYLCALIX[4]ARENES [J].

IWAMOTO, K ;

ARAKI, K ;

SHINKAI, S .

TETRAHEDRON, 1991, 47 (25) :4325-4342

[29] SYNTHESIS AND OPTICAL RESOLUTION OF A CHIRAL CALIX[4]ARENE ASYMMETRICALLY-SUBSTITUTED ON THE LOWER RIM [J].

IWAMOTO, K ;

YANAGI, A ;

ARIMURA, T ;

MATSUDA, T ;

SHINKAI, S .

CHEMISTRY LETTERS, 1990, (10) :1901-1904

[30]

IWAMOTO K, 1960, TETRAHEDRON LETT, V31, P7169

← 1 2 3 4 5 6 →