REGIOSELECTIVE BAEYER-VILLIGER REACTION OF POLYHYDROXYCYCLOHEXANONE DERIVATIVES

被引：33

作者：

CHIDA, N

TOBE, T

OGAWA, S

机构：

[1] Department of Applied Chemistry, Faculty of Science and Technology, Keio University, Kohoku-ku, Yokohama, 223, 3-14-1, Hiyoshi

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 39期

关键词：

D O I：

10.1016/0040-4039(94)85373-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The regioselectivities observed in Baeyer-Villiger reaction of polyhydroxycyclohexanone derivatives possessing various substituents at adjacent carbons to the ketone carbonyl are reported. This study suggested that the trend of the migratory aptitude of substituted carbons would be a carbon with benzyloxy > methoxy > ketal oxygen >> acyloxy similar to methyl.

引用

页码：7249 / 7252

页数：4

共 16 条

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