NEW APPLICATION OF THE MITSUNOBU REACTION FOR THE PREPARATION OF (DELTA-2) DERIVATIVES IN TERPENIC SERIES

被引:12
作者
ARANDA, G
LALLEMAND, JY
AZERAD, R
MAURS, M
CORTES, M
RAMIREZ, H
VERNAL, G
机构
[1] UNIV PARIS 05,CNRS,CHIM & BIOCHIM PHARMACOL & TOXICOL LAB,F-75270 PARIS 06,FRANCE
[2] PONTIFICIA UNIV CATOLICA CHILE,FAC QUIM,SANTIAGO,CHILE
关键词
D O I
10.1080/00397919408010564
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Application of the Mitsunobu reaction to various 3 beta-(equatorial)-hydroxy-4,4-dimethyl terpenic compounds provides the 2-ene-derivatives in good yields. A discussion about the mechanisms involved, and full details on the modified experimental protocol are given.
引用
收藏
页码:2525 / 2535
页数:11
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