NICKEL-CATALYZED SUBSTITUTION-REACTIONS OF ALLYLIC CARBONATES WITH ARYL-BORATES AND ALKENYL-BORATES

被引：62

作者：

KOBAYASHI, Y

IKEDA, E

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 15期

关键词：

D O I：

10.1039/c39940001789

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Substitution reactions of 1,3-disubstituted allylic carbonates 3 with aryl- and alkenyl-borates 4 are catalysed by [NiCl2(dppf)][dppf = 1,1'-bis(diphenylphosphino)ferrocene], and in the case of the cyclic carbonate 7, the reaction proceeds with complete inversion.

引用

页码：1789 / 1790

页数：2