EVIDENCE FOR A GAUCHE MINOR CONFORMER OF 1,3-BUTADIENE

被引：68

作者：

ENGELN, R ^{[1
]}

CONSALVO, D ^{[1
]}

REUSS, J ^{[1
]}

机构：

[1] UNIV ROME LA SAPIENZA,DIPARTIMENTO CHIM,I-00185 ROME,ITALY

来源：

CHEMICAL PHYSICS | 1992年 / 160卷 / 03期

关键词：

D O I：

10.1016/0301-0104(92)80010-S

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We present experimental Raman data on torsional transitions that prove that the less stable conformer of 1,3-butadiene has a gauche structure. It is shown that in order to predict the relative intensities of the "gauche" transitions with respect to the "trans" transitions, one has to include a second-order term in the Fourier expansion of the molecular polarizability.

引用

页码：427 / 433

页数：7

共 18 条

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