GENERALIZATION OF THE UDCA THEORY AND ITS APPLICATION TO THE ANALYSIS OF THE ION-FREE LAYER THICKNESS

被引:6
作者
ANDREU, R
MOLERO, M
CALVENTE, JJ
CARBAJO, J
机构
[1] Departamento de Química Física, Universidad de Sevilla
来源
JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1993年 / 358卷 / 1-2期
关键词
D O I
10.1016/0022-0728(93)80430-P
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The modified Gouy-Chapman theory with two planes of closest approach is generalized for any electrolyte stoichiometry, considering also the influence of the interfacial dielectric constant. Application is made to some experimental systems to derive the cation and anion distances of closest approach from the ion-free layer thickness.
引用
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页码:49 / 62
页数:14
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