SYNTHESIS OF HOMO-BIMETALLIC AND HETEROBIMETALLIC COMPLEXES INCORPORATING THE [(ETA(5)-C5H4)CME2(ETA(5)-C9H6)] LIGAND

被引：34

作者：

DIAMOND, GM

GREEN, MLH

POPHAM, NA

CHERNEGA, AN

机构：

[1] UNIV OXFORD,INORGAN CHEM LAB,S PARKS RD,OXFORD OX1 3QR,ENGLAND

[2] CHEM CRYSTALLOG LAB,OXFORD OX1 3PD,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 06期

关键词：

D O I：

10.1039/c39940000727

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The new bimetallic complexes [(eta5-C5H5)MCl2{(eta5-C5H4)CMe2(eta5-C9H6)}M*Cl2(eta5-C5H5)] (M = Zr, M* = Zr, Hf; M = Hf, M- = Zr, Hf), [(eta5-C5H5)ZrCl2{(eta5-C5H4)CMe2(eta5-C9H6)}ZrCl2(eta5-C5Me5)], [(eta5-C5H5)ZrCl2{(eta5-C5H4)CMe2(eta5-C9H6)}Rh(CO)2] and [(eta5-C5H5)ZrCl2{(eta5-C5H4)CMe2(eta5-C9H6)}Mn(CO)3] have been prepared from the precursors [{Me2C(eta5-C5H4)(eta2-C9H6)}M(eta5-C5H5)Cl] (M = Zr 1, Hf 2); the X-ray crystal structure of 1 is reported.

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页码：727 / 728

页数：2

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