STRUCTURAL EFFECTS IN SOLVOLYTIC REACTIONS .24. SOLVOLYSIS OF 1-CYCLOALKYL-L-ARYL-L-ETHYL PARA-NITROBENZOATES - EFFECT OF ALPHA-CYCLOALKYL GROUPS IN STABILIZING AN ELECTRON-DEFICIENT CENTER AS REVEALED BY TOOL OF INCREASING ELECTRON DEMAND

被引：13

作者：

BROWN, HC

RAVINDRANATHAN, M

RAO, CG

机构：

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1978年 / 100卷 / 04期

关键词：

D O I：

10.1021/ja00472a031

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

收藏

页码：1218 / 1222

页数：5

相关论文

共 21 条

[1] BARTLETT PD, 1963, J ORG CHEM, V28, P3351
[2] Brown H. C, 1977, NONCLASSICAL ION PRO
[3] DIRECTIVE EFFECTS IN AROMATIC SUBSTITUTION .30. ELECTROPHILIC SUBSTITUENT CONSTANTS
BROWN, HC
OKAMOTO, Y
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (18) : 4979 - 4987
[4] STRUCTURAL EFFECTS IN SOLVOLYTIC REACTIONS .17. SOLVOLYSIS OF 1-ARYL-1-CYCLOPROPYL-1-ETHYL P-NITROBENZOATES - EVIDENCE FOR MAJOR INCREASES IN ELECTRON SUPPLY BY CYCLOPROPYL GROUP WITH INCREASING ELECTRON DEMAND AT CATIONIC CENTER - EFFECT OF SUBSTITUENTS ON CYCLOPROPANE RING - SIGMA CONJUGATION VS SIGMA PARTICIPATION
BROWN, HC
PETERS, EN
RAVINDRANATHAN, M
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (02) : 505 - 509
[5] STRUCTURAL EFFECTS IN SOLVOLYTIC REACTIONS .22. EFFECT OF RING SIZE ON STABILIZATION OF DEVELOPING CARBOCATIONS AS REVEALED BY TOOL OF INCREASING ELECTRON DEMAND
BROWN, HC
RAVINDRANATHAN, M
PETERS, EN
RAO, CG
RHO, MM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (16) : 5373 - 5378
[6] SOLVOLYSIS OF 3-ARYL-3-NORTRICYCLYL P-NITROBENZOATES - EVIDENCE FOR MAJOR INCREASES IN ELECTRON SUPPLY BY CYCLOPROPYL GROUP WITH INCREASING ELECTRON DEMAND AT CATIONIC CENTER
BROWN, HC
PETERS, EN
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (07) : 1927 - 1929
[7] STRUCTURAL EFFECTS IN SOLVOLYTIC REACTIONS .23. NEW SIGMA-+ CONSTANTS FOR ACTIVATING SUBSTITUENTS - SOLVOLYSIS OF 1-ARYL-1-CYCLOPROPYL 3,5-DINITROBENZOATES CONTAINING ACTIVATING SUBSTITUENTS IN ARYL GROUP - TOOL OF INCREASING ELECTRON DEMAND AND I-STRAIN
BROWN, HC
RAO, CG
RAVINDRANATHAN, M
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (23) : 7663 - 7667
[8] HIGH EXO - ENDO RATE RATIO AND PREDOMINANT EXO SUBSTITUTION IN SOLVOLYSIS OF 2-P-ANISYLNORBORNYL DERIVATIVES . CHARACTERISTICS OF A HIGHLY STABILIZED CLASSICAL NORBORNYL CATION
BROWN, HC
TAKEUCHI, K
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (10) : 2691 - &
[9] STRUCTURAL EFFECTS IN SOLVOLYTIC REACTIONS .12. SOLVOLYSIS OF 2-ARYL-5-METHYL-2-NORBORNENYL-PARA-NITRO-BENZOATES AND 2,5-DIMETHYL-2-NORBORNENYL PARA-NITROBENZOATES - EVIDENCE FOR MAJOR PI PARTICIPATION REVEALED BY TOOL OF INCREASING ELECTRON DEMAND
BROWN, HC
PETERS, EN
RAVINDRANATHAN, M
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (26) : 7449 - 7453
[10] BROWN HC, 1952, J AM CHEMICAL SOC, V74, P1896