STRUCTURAL EFFECTS IN SOLVOLYTIC REACTIONS .23. NEW SIGMA-+ CONSTANTS FOR ACTIVATING SUBSTITUENTS - SOLVOLYSIS OF 1-ARYL-1-CYCLOPROPYL 3,5-DINITROBENZOATES CONTAINING ACTIVATING SUBSTITUENTS IN ARYL GROUP - TOOL OF INCREASING ELECTRON DEMAND AND I-STRAIN

被引：41

作者：

BROWN, HC ^{[1
]}

RAO, CG ^{[1
]}

RAVINDRANATHAN, M ^{[1
]}

机构：

[1] PURDUE UNIV,RICHARD B WETHERILL LAB,W LAFAYETTE,IN 47907

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1977年 / 99卷 / 23期

关键词：

D O I：

10.1021/ja00465a040

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：7663 / 7667

页数：5

共 27 条

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[3] STRUCTURAL EFFECTS IN SOLVOLYTIC REACTIONS .22. EFFECT OF RING SIZE ON STABILIZATION OF DEVELOPING CARBOCATIONS AS REVEALED BY TOOL OF INCREASING ELECTRON DEMAND
BROWN, HC
RAVINDRANATHAN, M
PETERS, EN
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[4] DIRECTIVE EFFECTS IN AROMATIC SUBSTITUTION .26. RATES OF SOLVOLYSIS OF THE META-PHENYL AND PARA-PHENYL, META-METHYLTHIO AND PARA-METHYLTHIO AND META-TRIMETHYLSILYLPHENYLDIMETHYLCARBINYL AND PARA TRIMETHYLSILYLPHENYLDIMETHYLCARBINYL CHLORIDES - STERIC INHIBITION OF RESONANCE AS A FACTOR IN ELECTROPHILIC SUBSTITUENT CONSTANTS
BROWN, HC
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[5] SOLVOLYSIS OF 3-ARYL-3-NORTRICYCLYL P-NITROBENZOATES - EVIDENCE FOR MAJOR INCREASES IN ELECTRON SUPPLY BY CYCLOPROPYL GROUP WITH INCREASING ELECTRON DEMAND AT CATIONIC CENTER
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[6] SOLVOLYSIS OF 2-ARYL-2-BICYCLO[2.1.1]HEXYL PARA-NITROBENZOATES - EVIDENCE FOR ABSENCE OF SIGMA-PARTICIPATION BY APPLICATION OF TOOL OF INCREASING ELECTRON DEMAND
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[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (07) : 2359 - 2361
[7] HIGH EXO - ENDO RATE RATIO AND PREDOMINANT EXO SUBSTITUTION IN SOLVOLYSIS OF 2-P-ANISYLNORBORNYL DERIVATIVES . CHARACTERISTICS OF A HIGHLY STABILIZED CLASSICAL NORBORNYL CATION
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[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (10) : 2691 - &
[8] STRUCTURAL EFFECTS IN SOLVOLYTIC REACTIONS .21. SOLVOLYSIS OF 2-ARYL-2-NORBORNYL AND 2-ARYL-2-CAMPHENILYL PARA-NITROBENZOATES - CRITICAL-EXAMINATION OF IMPORTANCE OF SIGMA-PARTICIPATION IN SOLVOLYSIS TERTIARY 2-NORBORNYL DERIVATIVES BY APPLICATION OF TOOL OF INCREASING ELECTRON DEMAND
BROWN, HC
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[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (08) : 2684 - 2690
[9] EFFECT OF COPLANARITY ON RATES OF SOLVOLYSIS OF SEVERAL T-CUMYL CHLORIDE DERIVATIVES - ELECTROPHILIC SUBSTITUENT CONSTANTS FOR POLYCYCLIC AROMATICS
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[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1961, 83 (23) : 4825 - &
[10] BROWN HC, 1952, J AM CHEMICAL SOC, V74, P1896

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