DIANION AND TETRAANION OF OCTALENE

被引：30

作者：

MULLEN, K ^{[1
]}

OTH, JFM ^{[1
]}

ENGELS, HW ^{[1
]}

VOGEL, E ^{[1
]}

机构：

[1] UNIV COLOGNE,INST ORGAN CHEM,D-5000 COLOGNE 41,FED REP GER

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 03期

关键词：

D O I：

10.1002/anie.197902291

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reduction of octalene to anions is a challenging task since the structure of this (4n + 2)π‐system permits several possible charges distributions in the anions. On treatment with lithium, octalene gives the dianion 1a or 1b and ultimately the tetraanion 2 which has a perimerer with π‐bond delocalization resembling that of naphthalene. (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：229 / 231

页数：3