HIGH-PRESSURE NMR PROBES FOR THE INSITU INVESTIGATION OF GAS-LIQUID REACTIONS

被引:23
作者
WOELK, K
BARGON, J
机构
[1] Institute of Physical Chemistry, University of Bonn, D-5300 Bonn-1
关键词
D O I
10.1063/1.1142543
中图分类号
TH7 [仪器、仪表];
学科分类号
0804 ; 080401 ; 081102 ;
摘要
Three different types of nuclear magnetic resonance (NMR) probes have been developed for investigating multiple phase (gas/liquid) reactions in situ at ambient and high pressure. Versions requiring only minimal modifications of existing NMR probes, low volume probes, and high precision flow systems have been optimized for specific boundary conditions. Pressures ranging from 1 to 20 bar have been successfully applied. The arrangements are especially attractive for the in situ investigations of homogeneous hydrogenation reactions displaying nuclear spin polarization.
引用
收藏
页码:3307 / 3310
页数:4
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