Potential curves of alkali diatomic molecules and the origins of bonding anomalies

被引：35

作者：

Roach, A. C. ^{[1
]}

Baybutt, P. ^{[1
]}

机构：

[1] Univ Manchester, Dept Chem, Manchester M13 9PL, Lancs, England

来源：

CHEMICAL PHYSICS LETTERS | 1970年 / 7卷 / 01期

关键词：

D O I：

10.1016/0009-2614(70)80234-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A previously developed model leads to calculated potential curves for Na-2, Na-2(+), K-2, K-2(+), NaK nnd NaK+ to an accuracy of around 2 kcal mole(-1), The anamalous relative strengths of one-electron and two-elctron bonds in these molecules are explained in terms of the Pauli exclusion effects arising from the presence of core electrons.

引用

页码：7 / 10

页数：4

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