LIQUID - LIQUID EQUILIBRIA IN HYDROCARBON PLUS 3-METHOXYPROPIONITRILE SYSTEMS, CORRELATION AND PREDICTION

被引：5

作者：

ANTOSIK, M

MALANOWSKI, S

机构：

来源：

FLUID PHASE EQUILIBRIA | 1993年 / 85卷

关键词：

EXPERIMENTS; DATA; LIQUID-LIQUID; MIXTURES; TERNARY; CORRELATIONS; HYDROCARBONS; 3-METHOXYPROPIONITRILE;

D O I：

10.1016/0378-3812(93)80011-B

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Liquid-liquid equilibria (LLE) for ternary system n-hexadecane + butylbenzene + 3-methoxypropionitrile (3MOPN) at 298.15 K are reported. These experimental results and earlier published ones dealing with mixtures of other hydrocarbons and 3MOPN were correlated using the NRTL and the UNIQUAC equations. The UNIFAC-LLE parameters for the some hydrocarbons groups with 3MOPN were calculated from experimental binary and ternary LLE. The prediction of liquid-liquid equilibria for ternary hydrocarbons + 3MOPN systems were compared with the experimental data.

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页码：161 / 170

页数：10

相关论文

共 15 条

[1] STATISTICAL THERMODYNAMICS OF LIQUID-MIXTURES - NEW EXPRESSION FOR EXCESS GIBBS ENERGY OF PARTLY OR COMPLETELY MISCIBLE SYSTEMS [J].

ABRAMS, DS ;

PRAUSNITZ, JM .

AICHE JOURNAL, 1975, 21 (01) :116-128

[2] MEASUREMENT OF PHASE-EQUILIBRIUM IN MULTICOMPONENT SYSTEMS OF AROMATICS WITH N-METHYLPYRROLIDONE AND PREDICTIONS WITH UNIFAC [J].

ALZAYIED, TA ;

ALSAHHAF, TA ;

FAHIM, MA .

FLUID PHASE EQUILIBRIA, 1990, 61 (1-2) :131-144

[3] TERNARY (LIQUID + LIQUID) EQUILIBRIA IN (NORMAL-DECANE + NORMAL-BUTYLBENZENE + 3-METHOXYPROPIONITRILE) [J].

ANTOSIK, M .

JOURNAL OF CHEMICAL THERMODYNAMICS, 1990, 22 (01) :85-89

[4] LIQUID LIQUID EQUILIBRIA IN TERNARY ALPHA-PINENE + DELTA-3-CARENE + POLAR COMPOUND SYSTEMS [J].

ANTOSIK, M ;

STRYJEK, R .

FLUID PHASE EQUILIBRIA, 1992, 71 (03) :321-331

[5] MUTUAL SOLUBILITY OF BINARY TRANS-DECALIN +, AND NORMAL-DECANE + POLAR COMPONENT MIXTURES [J].

ANTOSIK, M ;

STAFIEJ, A ;

STRYJEK, R .

FLUID PHASE EQUILIBRIA, 1990, 58 (03) :325-333

[6]

ANTOSIK M, 1993, IN PRESS J CHEM THER

[7]

FEDORKO M, 1980, POL J CHEM, V54, P1949

[8] GROUP-CONTRIBUTION ESTIMATION OF ACTIVITY-COEFFICIENTS IN NONIDEAL LIQUID-MIXTURES [J].

FREDENSLUND, A ;

JONES, RL ;

PRAUSNITZ, JM .

AICHE JOURNAL, 1975, 21 (06) :1086-1099

[9] MICROWAVE-SPECTRUM OF 3-METHOXYPROPIONITRILE [J].

LOWE, RS ;

KEWLEY, R .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1976, 63 (02) :216-226

[10] UNIFAC PARAMETER TABLE FOR PREDICTION OF LIQUID-LIQUID EQUILIBRIA [J].

MAGNUSSEN, T ;

RASMUSSEN, P ;

FREDENSLUND, A .

INDUSTRIAL & ENGINEERING CHEMISTRY PROCESS DESIGN AND DEVELOPMENT, 1981, 20 (02) :331-339