ISOLATION OF A REMARKABLY STABLE HYDROGEN-BONDED DIMERIC MANGANESE(II) COMPLEX, [MN(L)(OH2)](2)(ME(2)SO)(2) FROM THE REDUCTION OF A MANGANESE(III) SCHIFF-BASE COMPLEX [L=THE DIANION OF N,N'-BIS(3-BROMO-5-NITROSALICYLIDENE)-1,2-DIAMINO-(2-METHYL)ETHANE]

被引：19

作者：

BERMEJO, MR ^{[1
]}

GARCIADEIBE, A ^{[1
]}

SANMARTIN, J ^{[1
]}

SOUSA, A ^{[1
]}

AURANGZEB, N ^{[1
]}

HULME, CE ^{[1
]}

MCAULIFFE, CA ^{[1
]}

PRITCHARD, RG ^{[1
]}

WATKINSON, M ^{[1
]}

机构：

[1] UNIV MANCHESTER,INST SCI & TECHNOL,DEPT CHEM,MANCHESTER M60 1QD,LANCS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 05期

关键词：

D O I：

10.1039/c39940000645

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structure of [Mn(L)(OH2)](2)(Me(2)SO)(2) [L = the dianion of N,N'-bis(3-bromo-5-nitrosalicylidene)-1,2-diamino-(2-methyl)ethane] shows it to be a strongly hydrogen-bonded dimer of manganese(II), produced by recrystallisation of a manganese(III) Schiff base acetate complex from dimethyl sulfoxide.

引用

页码：645 / 646

页数：2

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