FREE-RADICALS IN THE OXIDATION AND HALOGENATION OF ALKANES BY DIMETHYLDIOXIRANE - AN OXYGEN REBOUND MECHANISM

被引：53

作者：

MINISCI, F

ZHAO, LH

FONTANA, F

BRAVO, A

机构：

[1] Dipartimento di Chimica del Politecnico, via Mancinelli

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 10期

关键词：

D O I：

10.1016/0040-4039(95)00048-H

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The oxidation of alkanes by dimethyldioxirane (DMD) in the presence of CBrCl3 provides strong evidence that free-radicals are involved in the reaction: enthalpic and polar effects and an ''oxygen rebound'' mechanism are suggested to explain the exceptional oxidation selectivity.

引用

页码：1697 / 1700

页数：4

共 17 条

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