SOLUBILITY OF SILVER CHLORIDE AND BROMIDE AND FORMATION OF SILVER HALIDE COMPLEXES IN MOLTEN AMMONIUM NITRATE DIHYDRATE

被引：14

作者：

GAL, IJ

机构：

来源：

INORGANIC CHEMISTRY | 1968年 / 7卷 / 08期

关键词：

D O I：

10.1021/ic50066a027

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The solubilities of silver chloride and bromide as a function of the corresponding ammonium halide concentration were determined in molten NH4NO3·2H2O, at 55, 70, and 85°. Solubility measurements were made using a radioactive-tracer technique with 110Ag. The solubility product Ksp and the consecutive stability constants of the complexes AgX, AgX2-, and AgX3- (X- = Cl-, Br-) were computed. The results are discussed in terms of a quasi-lattice model of molten salts.

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页码：1611 / &

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